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One Piece (SONY) · Whiskey Peak & Little Garden · Episode 66
All Out Battle! Luffy vs. Zoro, Mysterious Grand Duel!
Luffy, who does not realize the town is full of bounty hunters, engages in a battle with Zoro after he discovers that Zoro attacked the townsfolk, while Mr. 5 and Miss Valentine head for Princess Vivi.
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